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Cardona was one of the Founding Directors of the Institute. He retired
in 2000. His department was mainly concerned with optical spectroscopy of
semiconductors and high-Tc
superconductors in the form of bulk samples, surface layers, and low-dimensional
structures like quantum wells, quantum dots and superlattices. Central to his
interests is electron-phonon interaction, a topic of particular relevance to
both material classes. Experimental methods used at present are Raman, hyper-Raman
and Brillouin scattering off and in resonance, hot luminescence, spectroscopic
ellipsometry (including synchrotron radiation as a source), optical measurements
in high magnetic fields and under high pressure, photoelectron spectroscopy,
scanning tunneling microscopy in ultra-high vacuum and X-ray techniques for
surface and interface structure analysis. Close collaborations with the
synchrotron laboratories in Hamburg (HASYLAB), Berlin (BESSY), Grenoble (ESRF)
and Brookhaven (NSLS), the high pressure, technology, molecular beam epitaxy
and crystal growth service groups at the MPI, the High Magnetic Field Laboratory
and the Institute Laue-Langevin (ILL) in Grenoble have enabled the group to extend
the variety of experimental techniques at its disposal. Surface X-ray diffraction
and X-ray standing wave measurements are carried out at HASYLAB, ESRF and NSLS,
while at BESSY a vacuum UV ellipsometer (5-35 eV) is operated. At NSLS a
Fourier ellipsometer for the far infrared spectral range has been built and
optimized for measurements of extremely small samples. At ILL neutron scattering
is used to study the lattice dynamics of isotopically pure and disordered single
crystals. There is also a substantial theoretical effort in computing the
electronic and vibronic band structure as well as electron-phonon coupling
parameters of the materials under investigation. Topics of recent activities
of the group are the vibrational and electronic properties of various compound
semiconductors and superlattices, in many cases with controlled isotopic
composition, the structure of semiconductor surfaces in the UHV and at the
electrolyte interface, as well as electronic Raman scattering processes and
crystal field excitations in high-Tc
superconductors. Considerable effort, partly in collaboration with the University
of California at Berkeley and the Kurchatov Institute (Moscow) and Simon Frazer
University (Vancouver), is spent in the growth and characterization of crystals
with tailor-made stable isotope composition which are used to investigate isotope
effects on a wide range of physical properties such as phonon dispersion, lattice
constant, electronic band structure or thermal conductivity (for cv and list of
publications see http://isihighlycited.com).
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